Infatuation Rules
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Why do attractive forces dominate?

Points for ATTRACTIVE FORCES are dominant: At high pressure the molecules do not strike the walls with full impact as they are dragged back by attractive forces. When molecules are farther away from each other(as Vreal > Videal) the attractive forces are dominant.

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Your arguments for attractive forces are not quite correct, particularly the first one, the other two are partly correct. The points for repulsive forces are more accurate but not completely correct. The intermolecular potential energy is fixed by the type of molecule and varies with separation between molecules (e.g. a Lennard-Jones potential). The potential well formed by the interaction is short-range. It is effectively zero at about four to six molecular diameters decreases to negative values as the molecules approach one another (negative energy is attractive) but rapidly becomes positive ( repulsive) when the molecules are effectively in contact.The potential is unaffected by temperature and pressure. The ratio $p\overline{V}/RT$ is called the compressibility ratio Z and is unity for an ideal gas. ($\overline V$ is the molar volume $V/n$). Ideal gases have no intermolecular potential, or size. Real gases differ primarily in their size and magnitude of their intermolecular potential energy and so deviations from $Z=1$ are to be expected. At all temperatures and pressures the molecules have an attractive potential that tries to pair up molecules, and repulsion on collision when the charge on the electrons in each molecule force them to repel one another. It is the competition between attraction, repulsion and kinetic energy at a give temperature that determines the shape of the $Z ~ vs. p$ plot. For molecules at low temperature the line of the graph $Z= p\overline{V}/RT$ vs. p dips down further below $Z=1$ than it does for the same molecules at higher temperatures. This is because at low temperatures the molecules have less kinetic energy ( so move more slowly) and are more influenced by attractive forces than at higher temperatures. This makes the actual volume of gas smaller than the ideal (as a larger fraction of molecules are paired up), which in turn makes Z smaller. Similarly, at a given temperature, a larger negative Z is seen in gases with a larger attractive interaction, say $\ce{CO2, CH4 or ethene}$ compared to those with smaller attraction, e.g. $\ce{He or H2}$ . At high temperature the molecules have more kinetic energy and so attractive interactions are relatively less important, and repulsion more so as the kinetic energy is larger. This makes the actual volume greater than the ideal and $Z>1$.

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“He heals the brokenhearted and binds up their wounds.” The Good News: No matter the source of your heartbreak, God can repair your wounds. "Peace I leave with you; my peace I give you. I do not give it to you as the world gives.

Heartbreak is one of the most uniquely painful human experiences. Whether you're experiencing grief after losing someone you love, or just broke up with a longterm partner, feeling heartbroken can be an all-consuming physical, mental, and emotional sensation that takes a toll on your hope to let love back in one day in the future. Bible verses for a broken heart can serve as healing scripture to get you through the darker days when depression controls your thoughts. A broken heart takes time to heal, but while you search for closure, God's love will help guide you forward until loving someone new feels safe again. Bible verses can provide strength when your heart is at its weakest point. They can comfort you when death takes a loved one and even impact a current relationship. Through the ups and downs, God's words and love remain strong, even when you have a troubled heart after a divorce, separation, or breakup. Falling out of love is an unfortunate emotional roller coaster most people experience at least once in their life. But these Bible verses for broken hearts will remind you that you are still worthy of love and capable of letting love back into your life when you are ready. For now, God's love is enough.

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