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What is the strongest type of van der Waals forces?

The strongest of the Van der Waals forces are dipole-dipole interactions. Dipole-dipole interactions are the attractive/repulsive forces that exist between two polar molecules (molecules with a permanent dipole).

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Have you ever been relaxing in bed a looked up to see a spider staring down at you? While your first thought might be about killing it, have you ever wondered how it could climb on the ceiling like that? Unless you have the powers of Spider-man, if you tried that yourself, you would fall off the wall before you even got to the ceiling. So how do they do it? The secret is Van der Waals forces. In this article, we will be learning all about these forces and how they work. Maybe after learning about them, you could also learn how to harness their power to climb (though I wouldn't recommend it!) This article covers the topic of Van der Waals forces

First, we will learn the definition of Van der Waals forces

Then, we will learn about the three types of Van der Waals forces: dipole-dipole, dipole-induced dipole, and London dispersion forces Lastly, we will cover why Van der Waals forces are so important, and we will also look at some examples of these forces in action Van der Waals Forces Definition For starters, let's take a look at the definition of Van der Waals forces. Van der Waals forces are the electrostatic attraction/repulsion between molecules with either permanent or temporary dipoles. Dipoles are a set of separated charges within an atom/molecule. They are caused by an uneven distribution of electrons. When a species has a dipole, it has a partial positive (δ+) and a partial negative (δ-) end. These poles act like those of a magnet and will attract opposite charges while repelling like ones. Van der Waals forces are essentially the pushing/pulling caused by these polar molecules coming close to each other.

Types of Van der Waals Forces

There are three types of Van der Waals forces that you need to be familiar with: Dipole-dipole interactions Dipole-induced dipole interactions London dispersion forces (Instantaneous dipole-induced dipole) these forces are classified by whether the two molecules/atoms interacting have a permanent or temporary dipole, which we will discuss later. Now, let's talk about each of these Van der Waals forces in detail.

Dipole-Dipole Interactions

The strongest of the Van der Waals forces are dipole-dipole interactions.

Dipole-dipole interactions are the attractive/repulsive forces that exist between two polar molecules (molecules with a permanent dipole). The way we determine whether a molecule is polar or not is based on electronegativity. Electronegativity is the tendency for an atom to pull electrons/electron density towards itself. Electronegativity increases the further to the top right (fluorine) an element is on the periodic table, it decreases the further you get to the bottom right (francium). The difference in electronegativity is what determines bond polarity. If two atoms have a difference >0.5 in electronegativity, then the bond is polar. However, if a molecule is symmetrical, the molecule itself will be non-polar since the polarities will cancel themselves out.

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Is hydrogen bond the strongest bond?

The strongest bond is F-H-F. The interaction between the electronegativity of the bound atom and hydrogen determines the strength of the hydrogen bond. Fluorine is the most electronegative element in the periodic table. As a result, the F-H-F bond will be the most powerful H bond.

In which of the following the hydrogen bond is strongest:

(a) F-H—F

(b) O-H—S

(c) S-H—F

(d) F-H–O

Answer: (a)

Explanation: Hydrogen Bonding

The formation of hydrogen bonds, a sort of attractive intermolecular force induced by the dipole-dipole interaction between a hydrogen atom bound to a strongly electronegative atom and another strongly electronegative atom nearby, is referred to as hydrogen bonding.

The strongest bond is F-H-F.

The interaction between the electronegativity of the bound atom and hydrogen determines the strength of the hydrogen bond. Fluorine is the most electronegative element in the periodic table. As a result, the F-H-F bond will be the most powerful H bond.

Hydrogen Fluoride Hydrogen Bonding

Fluorine, which has the highest electronegativity, forms the strongest hydrogen bond.

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